Pengaruh Laju Alir Biogas dan Ukuran Partikel Pembentuk Pelet terhadap Penyisihan Karbon Dioksida (CO2) dalam Biogas dengan Proses Adsorpsi - Desorpsi Menggunakan Adsorben Berbasis Zeolit Alam untuk Peningkatan Kualitas Biogas

Authors

  • Rivaldi Sidabutar Universitas Sumatera Utara
  • Bambang Trisakti Universitas Sumatera Utara
  • Irvan Universitas Sumatera Utara

DOI:

https://doi.org/10.32734/jtk.v12i1.10134

Keywords:

Pb(II) adsorption, desorption, adsorbent, zeolite, carbon dioxide

Abstract

Adsorption is the process of fluid molecules contacting the surface of a solid material. This study aims to remove carbon dioxide (CO2) gas in biogas using natural zeolite-based adsorbent pellets by adsorption and desorption of CO2 from the adsorbent using air. CO2 removal was carried out to determine the percentage of CO2 removal efficiency with variations in biogas flow rates (100 mL/minute, 300 mL/minute, and 500 mL/minute) and variations in the type of adsorbent pellets (particle size, activation time, calcination time, and dealumination activation treatment). Determination of the percentage of CO2 removal is carried out by flowing the biogas into the column and contacting it with the adsorbent continuously for 30 minutes and the output gas is collected in a gas collector to analyze the remaining CO2 content. The results showed that the best CO2 removal was 97.7% using an adsorbent with a particle size of 140 mesh, 4 hours of calcination, 90 minutes of activation time, and dealumination activation at a flow rate of 100 mL/minute. The breakthrough characteristic curve presents the characteristic “S” profile at constant flow rate (100 mL/minute).

Downloads

Download data is not yet available.

References

I. J. Dioha, C. Ikeme, T. Nafi’u, N. I. Soba, and M. B. S. Yusuf, “Effect of carbon to nitrogen ratio on biogas production,” Int. Res. J. Nat. Sci., vol. 2, no. 1, pp. 30–39, 2014.

P. G. Adinurani et al., “Optimization of concentration and EM4 augmentation for improving bio-gas productivity from Jatropha curcas Linn capsule husk,” Int. J. Renew. Energy Dev., vol. 3, no. 1, pp. 73–78, 2014,

Y. S. Madaki and L. Seng, “Palm oil mill effluent (POME) from Malaysia palm oil mills: Waste or resource,” Int. J. Sci. Environ. Technol., vol. 2, no. 6, pp. 1138–1155, 2013.

M. R. Al Mamun, M. R. Karim, M. M. Rahman, A. M. Asiri, and S. Torii, “Methane enrichment of biogas by carbon dioxide fixation with calcium hydroxide and activated carbon,” J. Taiwan Inst. Chem. Eng., vol. 58, pp. 476–481, 2015,

S. Mihic, “Biogas fuel for internal combustion engines,” Ann. Fac. Eng. Hunedoara, vol. 2, no. 3, pp. 179–190, 2004,

C. G. Galante, L. Pezzola, N. Priano, S. Scaramellini, and A. Sottocornola, Methane from biogas the process, cleaning and projects, TPG 4140 Natural Gas Semester Report, 2012.

F. Battista, D. Fino, and G. Mancini, “Optimization of biogas production from coffee production waste,” Bioresour. Technol., vol. 200, pp. 884–890, 2016,

S. J. J. Titinchi, M. Piet, H. S. Abbo, O. Bolland, and W. Schwieger, “Chemically modified solid adsorbents for CO2 capture,” Energy Procedia, vol. 63, pp. 8153–8160, 2014,

S. K. Wahono, R. Maryana, M. Kismurtono, K. Nisa, and C. D. Poeloengasih, “Modifikasi zeolit lokal Gunung Kidul sebagai upaya peningkatan performa biogas untuk pembangkit listrik,” Seminar Rekayasa Kimia Dan Proses, pp. D-11-1–D-11-6, 2010.

L. Wahyu, N. Setyaningsih, Z. I. Asmira, and N. C. W. Fitri, “Aktivasi dan aplikasi zeolit alam sebagai adsorben logam kromium dalam air limbah industri penyamakan kulit,” Eksergi, vol. 14, no. 1, pp. 7–11, 2017.

S. K. Wahono and W. A. Rizal, “Biogas filter based on local natural zeolite materials,” Int. J. Renew. Energy Dev., vol. 3, no. 1, pp. 1–5, 2014,

A. Yamliha, B. D. Argo, and W. A. Nugroho, “Pengaruh ukuran zeolit terhadap penyerapan karbondioksida (CO2) pada aliran biogas,” J. Bioproses Komod. Trop., vol. 1, no. 2, pp. 67–72, 2013.

S. Sriatun, O. A. Manasikana, and A. Darmawan, “Modifikasi zeolit alam dengan ligan edta untuk adsorpsi ion logam Pb2+ dan Cd2+,” J. Kim. Sains dan Apl., vol. 11, no. 2, pp. 43–47, 2008,

N. Hamidi, I. N. G. Wardana, and D. Widhiyanuriyawan, “Peningkatan kualitas bahan bakar biogas melalui proses pemurnian dengan zeolit alam,” J. Rekayasa Mesin, vol. 2, no. 3, pp. 227–231, 2011.

A. Alonso-Vicario et al., “Purification and upgrading of biogas by pressure swing adsorption on synthetic and natural zeolites,” Microporous Mesoporous Mater., vol. 134, pp. 100–107, 2010,

Sugiarto, T. Oerbandono, D. Widhiyanuriyawan, and F. S. P. Putra, “Purifikasi biogas sistem kontinyu menggunakan zeolit,” J. Rekayasa Mesin, vol. 4, no. 1, pp. 1–10, 2013.

L. Hauchhum and P. Mahanta, “Carbon dioxide adsorption on zeolites and activated carbon by pressure swing adsorption in a fixed bed,” Int. J. Energy Environ. Eng., vol. 5, no. 4, pp. 349–356, 2014,

D. A. Kesnawaty, “Uji kapasitas adsorpsi gas karbon monoksida (CO) menggunakan oksida logam dan karbon aktif, ” Skripsi, Universitas Indonesia, Depok, 2010.

S. Kutluay, O. Baytar, and Ö. Şahin, “Equilibrium, kinetic and thermodynamic studies for dynamic adsorption of benzene in gas phase onto activated carbon produced from elaeagnus angustifolia seeds,” J. Environ. Chem. Eng., vol. 7, no. 2, pp. 1–10, 2019,

M. Dutta, J. K. Basu, H. Faraz, N. Gautam, and A. Kumar, “Fixed-bed column study of textile dye direct blue 86 by using a composite adsorbent,” Sch. Res. Libr., vol. 4, no. 2, pp. 882–891, 2012.

F. M. Baena-Moreno, M. Rodríguez-Galán, F. Vega, T. R. Reina, L. F. Vilches, and B. Navarrete, “Converting CO2 from biogas and MgCl2 residues into valuable magnesium carbonate: A novel strategy for renewable energy production,” Energy, vol. 180, pp. 457–464, 2019,

M. A. I. Sarker, “Equilibrium and mass transfer behaviour of CO2 adsorption on zeolites, carbon molecular sieve, and activated carbons,” Thesis, University of Regina, Regina, 2012.

Published

2023-03-24