Karakteristik Sifat Fisik Membran Elektrolit Polimer Berbasis Kitosan Larva Black Soldier Fly/Polivinil Alkohol/Poliakrilonitril dengan Penambahan Ammonium Klorida

Authors

  • Muhammad Thoriq Al Fath Universitas Sumatera Utara
  • Nisaul Fadilah Dalimunthe Universitas Sumatera Utara
  • Rivaldi Sidabutar Universitas Sumatera Utara
  • Michael Universitas Sumatera Utara
  • Rosma Natalia Samosir Universitas Sumatera Utara
  • Thiodorus Marvin Tjandra Universitas Sumatera Utara

DOI:

https://doi.org/10.32734/jtk.v13i1.15595

Keywords:

black soldier fly, chitosan, membrane, physical characteristics, polymer electrolyte

Abstract

Black soldier fly larvae shells/BSF-based chitosan can be utilized as polymer electrolyte membrane. This research aims to analyze the physical characteristics of BSF chitosan/PVA/PAN/NH4Cl by varying amount of chitosan and ratio of PVA: PAN. Membrane was fabricated using the phase inversion method. Polymer electrolyte with a mixture of 1.20 g of PVA/PAN with ratio variations of 10:90 and 20:80 and chitosan variations of 2.4 g; 2.8 g; and 3.2 g. Chitosan was also FTIR-characterized. Density and wáter absorption of polymer electrolyte with chitosan composition of 2.4 g; 2.8 g; 3.2 g and PVA/PAN ratio of 10:90 were 0.824 g/mL; 1 g/mL and 1.51 g/mL and water absorption 28.571%; 38.333%; and 46.154%, respectively; and at PVA/PAN ratio of 20:80 were 0.734 g/mL; 1.03 g/mL and 1.096 g/mL and water absorption 62.5%; 66.667% dan 100%, respectively. Best physical property was obtained with the incorporation of 2.4 g of chitosan and 10:90 PVA/PAN ratio.

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References

Masthura, N. Putri, and A. H. Daulay, “Analisis pengaruh penambahan volume dan lama fermentasi terhadap kelistrikan biobaterai sari buah nenas (Ananas comosus),” J. Fisika dan Terapannya, vol. 8, pp. 25–31, 2021

N. Shofiyana, I. Supriyadi, M. Uwais, and A. Qarni, “Transisi energi indonesia pasca pandemi covid-19 dan konflik militer rusia-ukraina,” J. Kewarganegaraan, vol. 6, no. 2, pp. 3381–3387, 2022.

M. Abidin, A. F. Hafidh, M. Widyaningsih, M. Yusuf, and A. Murniati, “Pembuatan biobaterai berbasis ampas kelapa dan tomat busuk,” J. Al Kimiya, vol. 7, no. 1, pp. 28–34, 2020.

K. Mohan et al., “Recent insights into the extraction, characterization, and bioactivities of chitin and chitosan from insects,” Trends Food Sci. Technol., vol. 105, no. August, pp. 17–42, 2020.

F. Safitri and I. Supu, “Uji konduktivitas film dan elektrolit polimer kitosan cangkang kepiting dengan penambahan KCl,” Jambura Phy. J., vol. 1, no. 2, pp. 99–109, 2019.

D. E. Pratiwi, “Sintesis membran elektrolit padat berbahan dasar kitosan,” J. Sainsmat, vol. 7, no. 2, pp. 86–91, 2018.

R. A. Lusiana, V. D. A. Sangkota, and S. J. Santosa, “Chitosan succinate / PVA-PEG membrane: Preparation, characterization, and permeation ability test on creatinine,” J. of Sci. & Appl. Chem., vol. 21, no. 2, pp. 80–84, 2018.

C. Juliano and G. A. Magrini, “Cosmetic ingredients as emerging pollutants of environmental and health concern. A mini-review,” Cosmetics (MDPI), vol. 4, no. 2, 2017.

C. He, J. Liu, J. Li, F. Zhu, and H. Zhao, “Blending based polyacrylonitrile/poly(vinyl alcohol) membrane for rechargeable lithium ion batteries,” J. Memb. Sci., vol. 560, no. May, pp. 30–37, 2018.

E. Szymanska and K. Winnicka, “Stability of chitosan -A challenge for pharmaceutical and biomedical applications,” Marine Drugs (MDPI), vol. 13, no. 4, pp. 1819–1846, 2015.

N. Mamajan Khan, N. S. Mohd Ali, A. F. Ahmad Fuzlin, and A. S. Samsudin, “Ionic conductiviy of alginate-NH4Cl polymer electrolyte,” Makara J. Technol., vol. 24, no. 3, pp. 125-130, 2020.

M. Purwanto, L. Atmaja, M.T. Salleh, M.A. Mohamed, J. Jafaar, A.F. Ismail, M. Santoso, dan N. Widiastuti, “Correlation between proton conductivity, hydrophilicity, and thermal stability of chitosan/montmorillonite composite membrane modified gptms and their performance in direct methanol fuel cell,” Malaysian J. Anal. Sci., vol. 21, no. 3, pp. 675–689, 2017.

S. N. Asnin, Wahab, D. Permana, L. O. Ahmad, S. H. Sabarwati, and L. O. A. Ramadhan, “Enhanced conductivity and ion exchange capacity of chitosan membranes through modification with lithium for lithium polymer battery application,” WSEAS Trans. Power Syst., vol. 11, pp. 183–189, 2016.

N. Widiarti, W. Sumarni, and L. Setyaningrum, “The synthesis of chitosan polymer membrane/PVA as an eco-friendly battery for alternative energy resource,” J. Bahan Alam Terbarukan, vol. 6, no. 1, pp. 14–19, 2017.

B. Buanasari, W. Sugiyo, and H. Rustaman, “Effect of ultrasonic assisted on the degree of deacetylation of chitosan extracted from portunus pelagicus,” J. Bahan Alam Terbarukan, vol. 10, no. 1, pp. 17–23, 2021.

S. A. Agrawal, “Simplified measurement of density of irregular shaped composites material using archimedes principle by mixing two fluids having different densities,” Int. Res. J. Eng. Technol., vol. 8, no. 3, pp. 1005–1009, 2021.

A. Pambudi, M. Farid, and H. Nurdiansah, “Analisa morfologi dan spektroskopi infra merah serat bambu betung (Dendrocalamus asper) hasil proses alkalisasi sebagai penguat komposit absorbsi suara,” J. Tek. ITS, vol. 6, no. 2, pp. 441–444, 2017.

R. Modaso, E. Suryanto, T. Tallei, and I. F. . Rumengan, “The yield, nitrogen content, and dye’s binding capacity of chitin and chitosan of rotifer Brachionus rotundiformis,” Aquat. Sci. Manag., vol. 106, no. Mei, p. 99, 2013.

S. Wahyuni, R. Selvina, R. Fauziyah, H. T. Prakoso, P. Priyono, and S. Siswanto, “Optimasi suhu dan waktu deasetilasi kitin berbasis selongsong maggot (Hermetia ilucens) menjadi kitosan,” J. Ilmu Pertan. Indones., vol. 25, no. 3, pp. 373–381, 2020.

R. Ardianto and R. Amalia, “Optimasi proses deasetilasi kitin menjadi kitosan dari selongsong maggot menggunakan RSM,” Metana, vol. 19, no. 1, pp. 1–12, 2023.

F. Khoushab and M. Yamabhai, “Chitin research revisited,” Mar. Drugs, vol. 8, no. 7, pp. 1988–2012, 2010.

P. Wan, X. Yang, Q. Feng, S. Shi, B. Deng, and L. Zhang, “Biodegradable chitosan-based membranes for highly effective separation of emulsified oil/water,” Environ. Eng. Sci., vol. 39, no. 12, pp. 907–917, 2022.

H. J. Kim, S. J. Park, D. I. Kim, S. Lee, O. S. Kwon, and I. K. Kim, “Moisture effect on particulate matter filtration performance using electro-spun nanofibers including density functional theory analysis,” Sci. Rep., vol. 9, no. 1, pp. 1–8, 2019.

L. Fan, M. Wang, Z. Zhang, G. Qin, X. Hu, and Q. Chen, “Preparation and characterization of PVA alkaline solid polymer electrolyte with addition of bamboo charcoal,” Materials (Basel)., vol. 11, no. 5, 2018.

G. Zhu, F. Wang, K. Xu, Q. Gao, and Y. Liu, “Study on properties of poly(vinyl alcohol)/polyacrylonitrile blend film,” Polimeros, vol. 23, no. 2, pp. 146–151, 2013.

A. P. Dewi, A. Mardhiyana, R. Manfaati, and U. Leoanggraini, “The effect of additional chitosan and cellulose on the performance of bioplastic from manihot glaziovii starch,” Fluida, vol. 16, no. 1, pp. 36–42, 2023.

R. Syafri et al., “Synthesis and characterization of polymer electrolyte membrane based on cellulose-chitosan-alginate as Li-ion battery separator,” Int. J. Adv. Sci. Eng. Inf. Technol., vol. 13, no. 2, pp. 585–591, 2023.

Published

2024-03-23