Adsorpsi Ion Amonium dari Larutan Encer Menggunakan Zeolit Alam Sarulla Termodifikasi KCl
DOI:
https://doi.org/10.32734/jtk.v14i1.16240Keywords:
natural zeolite, ammonium, kinetic model, adsorption isothermAbstract
This study aims to evaluate the effectiveness of KCl-modified Sarulla natural zeolite in removing ammonium ions from aqueous solutions. The zeolite was modified by soaking in 0.5 M (ZA05) and 1.5 M (ZA15) KCl solutions for 24 hours at a solid/solvent ratio of 1:3 (weight/volume). The adsorption process was conducted in batch mode using an orbital shaker at a speed of 100 rpm, with contact times ranging from 0 to 210 minutes. The initial ammonium ion concentration was 100 mg/L, and the analysis was performed using a UV-visible spectrophotometer. The results showed that ZA05 and ZA15 adsorbents achieved ammonium ion removal efficiencies of 14.62% and 12.29%, respectively. Adsorption isotherm analysis using the Langmuir and Freundlich models demonstrated a good fit with the equilibrium data, with ZA15 exhibiting a higher maximum adsorption capacity than ZA05. This study confirms the potential of KCl-modified Sarulla natural zeolite as an effective adsorbent material for wastewater treatment.
Downloads
References
S. K. Ong, Wastewater Engineering. 2007. doi: 10.1002/9780470168219.ch8.
Y. P. Li, C. Y. Tang, Z. B. Yu, and K. Acharya, “Correlations between algae and water quality: Factors driving eutrophication in Lake Taihu, China,” Int. J. Environ. Sci. Technol., vol. 11, no. 1, pp. 169–182, 2014, doi: 10.1007/s13762-013-0436-4.
H. Runtti et al., “Removal of Ammonium Ions from Aqueous Solutions Using Alkali-Activated Analcime as Sorbent,” ChemEngineering, vol. 7, no. 1, 2023, doi: 10.3390/chemengineering7010005.
V. K. Gupta, H. Sadegh, M. Yari, R. Shahryari Ghoshekandi, B. Maazinejad, and M. Chahardori, “Removal of ammonium ions from wastewater a short review in development of efficient methods,” Glob. J. Environ. Sci. Manag., vol. 1, no. 2, pp. 149–158, 2015, doi: 10.7508/gjesm.2015.02.007.
Q. Cheng et al., “Study on the adsorption of nitrogen and phosphorus from biogas slurry by NaCl-modified zeolite,” PLoS One, vol. 12, no. 5, pp. 1–12, 2017, doi: 10.1371/journal.pone.0176109.
M. K. Nizam, S. Azhari, and M. A. Tamar Jaya, “Modified Zeolite as Purification Material in Wastewater Treatment: A Review,” Sci. Res. J., vol. 18, no. 2, pp. 177–213, 2021, doi: 10.24191/srj.v18i2.12092.
M. Kuronen, M. Weller, R. Townsend, and R. Harjula, “Ion exchange selectivity and structural changes in highly aluminous zeolites,” React. Funct. Polym., vol. 66, no. 11, pp. 1350–1361, 2006, doi: 10.1016/j.reactfunctpolym.2006.03.019.
J. L. Sihombing, S. Gea, A. N. Pulungan, H. Agusnar, B. Wirjosentono, and Y. A. Hutapea, “The characterization of Sarulla natural zeolite crystal and its morphological structure,” AIP Conf. Proc., vol. 2049, no. December, 2018, doi: 10.1063/1.5082467.
L. Velarde, M. S. Nabavi, E. Escalera, M. L. Antti, and F. Akhtar, “Adsorption of heavy metals on natural zeolites: A review,” Chemosphere, vol. 328, no. March, p. 138508, 2023, doi: 10.1016/j.chemosphere.2023.138508.
J. Shi et al., “Preparation and application of modified zeolites as adsorbents in wastewater treatment,” Water Sci. Technol., vol. 2017, no. 3, pp. 621–635, 2017, doi: 10.2166/wst.2018.249.
J. Liu, X. Cheng, Y. Zhang, X. Wang, Q. Zou, and L. Fu, “Zeolite modification for adsorptive removal of nitrite from aqueous solutions,” Microporous Mesoporous Mater., vol. 252, pp. 179–187, 2017, doi: 10.1016/j.micromeso.2017.06.029.
M. Noroozifar, M. Khorasani-Motlagh, and H. Naderpour, “Modified nanocrystalline natural zeolite for adsorption of arsenate from wastewater: Isotherm and kinetic studies,” Microporous Mesoporous Mater., vol. 197, pp. 101–108, 2014, doi: 10.1016/j.micromeso.2014.05.037.
N. S. Dionisiou and T. Matsi, Natural and Surfactant-Modified Zeolite for the Removal of Pollutants (Mainly Inorganic) From Natural Waters and Wastewaters. Elsevier Inc., 2016. doi: 10.1016/B978-0-12-803837-6.00023-8.
W. R. Ansari, H. Harahap, and A. Husin, “Fixed-bed column adsorption performance for ammonia removal using adsorbent from zeolite,” IOP Conf. Ser. Mater. Sci. Eng., vol. 1122, no. 1, p. 012076, 2021, doi: 10.1088/1757-899x/1122/1/012076.
W. B. Sediawan, A. Prasetya, and T. Syarif, "Pemodelan matematis dan penyelesaian numeris dalam teknik kimia dengan pemrograman bahasa MATLAB, ". J. Ilmu Pendidik., vol. 7, no. 2, pp. 809–820, 2020.
K. Y. Foo and B. H. Hameed, “Insights into the modeling of adsorption isotherm systems,” Chem. Eng. J., vol. 156, no. 1, pp. 2–10, 2010, doi: 10.1016/j.cej.2009.09.013.
N. Widiastuti, H. Wu, H. M. Ang, and D. Zhang, “Removal of ammonium from greywater using natural zeolite,” Desalination, vol. 277, no. 1–3, pp. 15–23, 2011, doi: 10.1016/j.desal.2011.03.030.
H. Guo, X. Zhang, and J. Liu, “Ion-exchange capability for ammonium removal using zeolite modified by potassium permanganate,” Chem. Eng. Trans., vol. 55, pp. 163–168, 2016, doi: 10.3303/CET1655028.
Downloads
Published
Issue
Section
License
Copyright (c) 2025 Jurnal Teknik Kimia USU

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.