Ekstraksi Silika dari Fly Ash Pabrik Kelapa Sawit Menggunakan Variasi Pelarut Karbonat

Authors

  • Regna Tri Jayanti Politeknik ATI Padang
  • Jerry Politeknik ATI Padang
  • Miftahurrahmah Politeknik ATI Padang

DOI:

https://doi.org/10.32734/jtk.v12i1.9850

Keywords:

extraction, silica, fly ash, carbonate, palm oil

Abstract

The selection of a catalyst is imperative in extracting silica. Calcium is a heterogeneous base catalyst that is abundant in carbonate rocks. This study attempts to extract silica using an artificial carbonate solvent with variations of strong acid HCl (1 M, 3 M, 5 M), NaCl salt (1: 2, 1: 4) w/w ratio to distilled water, and H2O (1: 4) w/w ratio to carbonate. Characteristics of fly ash were analyzed using XRF and XRD to determine the elemental composition, crystal structure, and dominant constituent compounds. The solvent concentration and pH effect in extracting silica from fly ash is reviewed by setting the temperature parameter at 60 C, 120 minutes extraction time, and the ratio between fly ash and carbonate solvent 20 % w/v. The filtrate was verified using UV-Vis to determine the concentration of dissolved silica (SiO2) in the carbonate solvent. The examination results showed that the carbonate solvent with 3 M HCl was able to extract silica better than the other five solvents at 68.17 ppm. 

Downloads

Download data is not yet available.

References

Tugiman, Suprianto, and R. Daulay, “Analisa Pemanfaatan Palm Oil Fly Ash sebagai Bahan Alternatif pada Pembuatan Metal Matrix Composite (MMC) Menggunakan Metode Stir Casting,†in Proceeding Seminar Nasional Tahunan Teknik Mesin XII (SNTTM XII), vol. 3, no. 23-24 pp. 1246–1251, 2013.

Bahruddin, A. Ahmad, A. Prayitno, and R. Satoto, “Morphology and Mechanical Properties of Palm Based Fly Ash Reinforced Dynamically Vulcanized Natural Rubber/Polypropylene Blends,†Procedia Chem., vol. 4, pp. 146–153, 2012.

K. Muthusamy, N. Zamri, M. A. Zubir, A. Kusbiantoro, and S. W. Ahmad, “Effect of mixing ingredient on compressive strength of oil palm shell lightweight aggregate concrete containing palm oil fuel ash,†Procedia Eng., vol. 125, pp. 804–810, 2015.

A. Munir, Abdullah, Huzaim, Sofyan, Irfandi, and Safwan, “Utilization of palm oil fuel ash (POFA) in producing lightweight foamed concrete for non-structural building material,†Procedia Eng., vol. 125, pp. 739–746, 2015.

Y. Pausa, “Optimasi Tingkat Kemurnian Silika, SiO2, dari Abu Cangkang Sawit Berdasarkan Konsentrasi Pengasaman,†Prism. Fis., vol. 3, no. 1, pp. 1–4, 2015.

V. Devra et al., “Pure Silica Extraction from Perlite: Its Characterization and Affecting factors,†Int. J. Innov. Res. Sci. Eng. Technol., vol. 2, 2013.

P. S. Utama, R. Yamsaengsung, and C. Sangwichien, “Production and Characterization of Precipitated Silica from Palm Oil Mill Fly Ash using CO2 Impregnation and Mechanical Fragmentation,†Brazilian J. Chem. Eng., vol. 36, no. 1, pp. 523–530, 2019.

D. Dhaneswara, J. F. Fatriansyah, F. W. Situmorang, and A. N. Haqoh, “Synthesis of Amorphous Silica from Rice Husk Ash: Comparing HCl and CH3COOH Acidification Methods and Various Alkaline Concentrations,†Int. J. Technol., vol. 11, no. 1, pp. 200–208, 2020.

A. F. Fadli, R. T. Tjahjanto, and Darjito, “Ekstraksi Silika dalam Lumpur Lapindo Menggunakan Metode Kontinyu,†Kim. Student J., vol. 1, no. 2, pp. 182–187, 2013.

V. V. Potapov, A. A. Cerdan, D. S. Gorev, S. V. Zubaha, and E. V. Shunina, “Silica Extraction from Hydrothermal Heat Carrier by Coagulation,†IOP Conf. Ser. Earth Environ. Sci., vol. 367, no. 1, 2019.

M. M. H. Al Omari, I. S. Rashid, N. A. Qinna, A. M. Jaber, and A. A. Badwan, “Calcium Carbonate,†in Profiles of Drug Substances, Excipients and Related Methodology, vol. 41, pp. 31–132, 2016.

Khalil and A. S, “Studi Komposisi Mineral Tepung Batu Bukit Kamang Sebagai Bahan Baku Pakan Sumber Mineral,†Media Peternak., vol. 30, no. 1, pp. 18–25, 2007.

I. Pratomo, S. Wardhani, and D. Purwonugroho, “Pengaruh Teknik Ekstraksi dan Konsentrasi HCl dalam Ekstraksi Silika dari Sekam Padi untuk Sintesis Silika Xerogel,†Kim. Studentjournal, vol. 2, no. 1, pp. 358–364, 2013.

J. F. Fatriansyah, F. W. Situmorang, and D. Dhaneswara, “Ekstraksi Silika dari Sekam Padi: Metode Refluks dengan NaOH dengan Pengendapan menggunakan Asam Kuat (HCl) dan Asam Lemah (CH3COOH),†Pros. Semin. Nas. Fis. Univ. Riau ke-3, vol. 5, no. 1, 2018.

A. Daulay, Andriayani, Marpongahtun, and S. Gea, “Extraction Silica from Rice Husk with NaOH Leaching Agent with Temperature Variation Burning Rice Husk,†Rasayan J. Chem., vol. 14, no. 3, pp. 2125–2128, 2021.

D. R. Mujiyanti, D. Ariyani, and N. Paujiah, “Kajian Variasi Konsentrasi NaOH dalam Ekstraksi Silika dari Limbah Sekam Padi Banjar Jenis ‘PANDAK,’†J. Sains dan Terap. Kim., vol. 15, no. 2, p. 143, 2021.

N. A. Zarib, S. A. Abdullah, and N. A. Jusri, “Effect of Acid Treatment on Extraction of Silica from Cogon Grass by Using C6H8O7 and HCL Acid,†IOP Conf. Ser. Mater. Sci. Eng., vol. 834, no. 1, 2020.

D. Amalia, M. Aziz, and Yuhelda, “Pengaruh Penambahan Kalsium Klorida, Kalsium Hidroksida dan Karbon Aktif Terhadap Penurunan Silika Terlarut dalam Larutan Sodium Aluminat,†Teknol. Miner. dan Batubara, vol. 9, no. September, pp. 157–164, 2013.

M. Mehmood, “Dolomite and dolomitization model - a short review,†Int. J. Hydrol., vol. 2, no. 5, pp. 549–553, 2018.

T. Tsuzuki, K. Pethick, and P. G. McCormick, “Synthesis of CaCO3 Nanoparticles by Mechanochemical Processing,†J. Nanoparticle Res., vol. 2, no. 4, pp. 375–380, 2000.

R. Revisdah and S. Mira, “Pengaruh Air Soda terhadap Kuat Tekan Beton,†Pros. SEMNASTEK Fak. Tek., vol. 4, no. November, p. 5, 2015.

H. Panggabean and D. Onggo, “Sintesis Gas Karbondioksida Menggunakan Alat Sintesis Gas Skala Kecil,†Snips, no. 2, pp. 366–370, 2017.

A. Royani, “Proses Pelarutan Bijih Dolomit dalam Larutan Asam Klorida,†Semin. Nas. Sains dan Teknol., vol. 1, no. 1, pp. 1–5, 2016.

W. Sumarni, D. Suhendar, and E. P. Hadisantoso, “Rekristalisasi Natrium Klorida dari Larutan Natrium Klorida Dalam beberapa Minyak yang Dipanaskan,†al-Kimiya, vol. 4, no. 2, pp. 100–104, 2019.

S. Annisa, G. Rachim, I. Raya, and M. Zakir, “Modifikasi Katalis CaO untuk Produksi Biodiesel dari Minyak Bekas,†Indo. J. Chem, vol. 5, no. 1, pp. 459–464, 2017.

M. H. A. Fatony, T. Haryati, and M. Mintadi, “Ekstraksi Silika dari Fly Ash Batubara (Studi Pengaruh Variasi Waktu Ekstraksi, Jenis Asam dan pH),†Pros. Semin. Nas. Kim., pp. 54–59, 2015.

Published

2023-03-24