Synthesis of MnFe2O4 Nanoparticles as a Basic Material for Microwave Absorber

Abstract

This work aimed to synthesize MnFe₂O₄ nanoparticles using the coprecipitation method. Manganese chloride dihydrate (MnCl₂.₄H₂O) and iron sand from South Cianjur, Indonesia, were used as a precursor for MnFe₂O₄ nanoparticle synthesis. The iron sand elements and compounds were tested using X-Ray Fluorescence (XRF). MnFe₂O₄ nanoparticle was characterized using X-Ray Diffraction (XRD), Scanning Electron Microscope-Energy Dispersive X-Ray (SEM-EDX), and Vector Network Analyzer (VNA). The X-Ray Fluorescence test result showed that 70.54% of South Cianjur contained iron sand. The SEM test result showed that the nanoparticles have an average size of  73.75 nm with a round shape, which was attributed to the agglomeration process. The EDX test result showed that the synthesized nanoparticle contained only Mn, Fe, and O elements without contaminants. The XRD test result showed that the crystal phase of MnFe₂O₄ was formed with a crystal size of less than 27 nm. The largest reflection losses in the 11.5 - 12.5 GHz range were found in MnFe₂O₄ with 1:2 variation, i.e., 35.08 dB. This study found that adding iron sand increases MnFe₂O₄ microwave absorption.