Performance Evaluation of Reactivated Spent Bleaching Earth on Color Reduction of Crude Palm Oil
DOI:
https://doi.org/10.32734/jcnar.v7i2.25586Keywords:
Crude Palm Oil, Reactivation, Spent Bleaching EarthAbstract
This study aims to evaluate the performance of reactivated Spent Bleaching Earth (SBE) in reducing the color of Crude Palm Oil (CPO). SBE was reactivated through chemical activation using HCl and H2SO4 in single, mixed, and sequential modes, followed by calcination at 600°C, producing Reactivated Spent Bleaching Earth (RSBE A–K) samples. The reactivated materials were characterized using Scanning Electron Microscopy (SEM) to evaluate their surface morphology before being applied to the CPO bleaching process and compared with fresh Bleaching Earth (BE). The results showed that the initial CPO color of 22.0/22.0 (red/yellow) was optimally reduced to 7.6/7.6 using RSBE I, outperforming fresh BE, which reduced the color to 11.0/11.0. RSBE I also exhibited the highest performance among all samples. SEM characterization showed that the reactivation process produced a cleaner surface morphology, supporting the improved adsorption performance of RSBE. These findings demonstrate the potential of reactivated SBE as an efficient and sustainable alternative adsorbent for the palm oil refining industry.
Downloads
References
[1] Nugraha, Iriany, and E. Misran, “Regeneration of spent bleaching earth using microwave assisted extraction method with hexane as solvent for the bleaching of crude palm oil,” in Journal of Physics: Conference Series, Institute of Physics, 2023. doi: 10.1088/1742-6596/2421/1/012007.
[2] GAPKI, “Palm Oil Industry Performance In 2023 and Prospects For 2024,” www.gapki.id.
[3] D. A. Iryani et al., “Reactivation of Spent Bleaching Earth using Acid-Activation and Calcination Treatment for Enhancing Adsorption Abilities and Reducing Environmental Loading in Palm Oil Refining Industries,” Chem. Eng. Trans., vol. 106, pp. 1327–1332, 2023, doi: 10.3303/CET23106222.
[4] H. T. Prakoso, A. S. S. Mawardanti, A. MAftuhah, F. Dimawarnita, Y. Faramitha, and B. Poerwadi, “Synthesis of Residual Oil from Spent Bleaching Earth (SBE) into Biodiesel using Microwave Reactor,” Jurnal Teknologi Industri Pertanian, pp. 185–192, Aug. 2024, doi: 10.24961/j.tek.ind.pert.2024.34.2.185.
[5] S. A. L. Bachmann, R. D. C. S. C. Valle, A. A. Vegini, and L. B. B. Tavares, “Determination of optimum conditions for thermal regeneration and characterization of a spent bleaching earth,” J. Environ. Chem. Eng., vol. 8, no. 2, Apr. 2020, doi: 10.1016/j.jece.2019.103503.
[6] S. F. A. Shattar, N. A. Zakaria, and K. Y. Foo, “One step acid activation of bentonite derived adsorbent for the effective remediation of the new generation of industrial pesticides,” Sci. Rep., vol. 10, no. 1, Dec. 2020, doi: 10.1038/s41598-020-76723-w.
[7] R. Viana Pinto Leal, R. Alves Lima Sobrinho, and M. Tramontin Souza, “Recycling diatomaceous earth waste: Assessing its physicochemical features, recovery techniques, applications, viability and market opportunities,” Mar. 01, 2025, Elsevier B.V. doi: 10.1016/j.clwas.2025.100244.
[8] S. M. Abdelbasir, A. I. Shehab, and M. A. A. Khalek, “Spent Bleaching earth; Recycling and Utilization Techniques: A review,” May 01, 2023, Elsevier Inc. doi: 10.1016/j.rcradv.2022.200124.
[9] American Oil Chemists Society, AOCS Official Method Cc 13e-92 Color of Fats and Oil - Lovibond Method Using Color Glasses Calibrated in Accordance with The Lovibond Tintometer Color Scale. 2024.
[10] I. K. Nugraheni et al., “Regeneration of Spent Bleaching Earth by Calcination and Its Morphological Enhancement via KOH Impregnation,” Indonesian Journal of Chemistry, vol. 26, no. 1, pp. 40–54, Jan. 2026, doi: 10.22146/IJC.99600.
[11] O. T. Handoko et al., “Economic and environmental analysis of spent bleaching earth reactivation,” in IOP Conference Series: Earth and Environmental Science, Institute of Physics, 2024. doi: 10.1088/1755-1315/1308/1/012061.
[12] R. Tetrisyanda and G. Wibawa, “Utilization of Oil Recovery Process on Spent Bleaching Earth into Non-Hazardous Waste,” Advances in Science and Technology, vol. 138, pp. 21–25, 2024, doi: 10.4028/P-GKR8K7.
[13] A. Yulikasari, E. Nurhayati, W. Utama, and I. Warmadewanthi, “Characterization of Spent Bleaching Earth as an Adsorbent Material for Dye Removal,” Journal of Ecological Engineering, vol. 23, no. 4, pp. 96–104, 2022, doi: 10.12911/22998993/146353.
[14] V. Plata, Ó. Rojas, and P. Gauthier-Maradei, “Improvement of palm oil biodiesel filterability by treatment with reactivated spent bleaching earths,” Fuel, vol. 260, p. 116198, Jan. 2020, doi: 10.1016/J.FUEL.2019.116198.
[15] F. E. Soetaredjo et al., “Ecological-safe and low-cost activated-bleaching earth: Preparation, characteristics, bleaching performance, and scale-up production,” J. Clean. Prod., vol. 279, Jan. 2021, doi: 10.1016/j.jclepro.2020.123793.
[16] S. Placxedes, M. Tirivaviri, Abdulkareem, S. Ambali, and D. Gwiranai, “Spent Bleaching Earth: Synthesis, Properties, Characterisation and Application,” J. Sustain. Sci. Manag., vol. 19, no. 3, pp. 192–220, Mar. 2024, doi: 10.46754/jssm.2024.03.014.
[17] W. T. Tsai, H. P. Chen, M. F. Hsieh, H. F. Sun, and C. W. Lai, “Regeneration of bleaching clay waste by chemical activation with chloride salts,” J. Environ. Sci. Health A Tox. Hazard. Subst. Environ. Eng., vol. 38, no. 4, pp. 685–696, 2003, doi: 10.1081/ESE-120016933,.
[18] K. Rahman, T. Ahmed, and A. Mahmood, “A Facile, Eco-Friendly and Cost-Effective Method for Regeneration of Spent Bleaching Earth,” SSRN Electronic Journal, Sep. 2022, doi: 10.2139/SSRN.4182278.
[19] A. Andronova et al., “Influence of acid and thermal treatment on regeneration of spent bleaching clay and conversion of residual oil to biodiesel,” J. Air Waste Manage. Assoc., vol. 74, no. 9, pp. 595–610, Sep. 2024, doi: 10.1080/10962247.2024.2365715.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Journal of Chemical Natural Resources

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.










