Synthesis and Characterization of Natural Pahae Zeolite–Durian Peel Activated Carbon as an Adsorbent for Phosphate Reduction in Laundry Wastewater

Authors

  • Susilawati Universita Sumatera Utara
  • Siti Fadhilah Universitas Sumatera Utara
  • Friska Anggraini Universitas Sumatera Utara

DOI:

https://doi.org/10.32734/jotp.v7i2.22735

Keywords:

Adsorption, Durian Peel Activated Carbon, Laundry Wastewater, Natural Pahae Zeolite, Phosphate

Abstract

This study aims to synthesize and characterize composites based on Pahae Natural Zeolite and Durian Peel Activated Carbon as phosphate reducers in laundry wastewater. Zeolite was activated using 1 M NaCl solution, while activated carbon was prepared by carbonization at 500 °C for 2 hours. The Zeolite–Activated Carbon mixtures were prepared with compositions of 100%:0%, 95%:5%, 90%:10%, 85%:15%, 80%:20%, 75%:25%, and 0%:100%, pressed at 6 tons for 10 minutes, and sintered at 700 °C, 800 °C, and 900 °C for 4 hours. Characterization included physical properties (porosity, water absorption), mechanical properties (hardness), morphology (SEM), crystal structure (XRD), and elemental composition (XRF). The results showed that the optimum condition was achieved at a 75%:25% composition and 700 °C, with porosity of 59.67%, water absorption of 56.06%, and phosphate reduction efficiency of 80.86%. The highest hardness value was obtained at 100%:0% composition at 900 °C, reaching 784.14 MPa. Therefore, the Pahae Natural Zeolite–Durian Peel Activated Carbon composite demonstrates potential as an effective and environmentally friendly adsorbent for wastewater treatment.

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References

D. Palilingan, R. Manurung, and J. Simanjuntak, “Pemanfaatan zeolit dan arang aktif untuk pengolahan air limbah laundry,” Jurnal Teknologi Lingkungan, vol. 20, no. 2, pp. 85–92, 2019.

Kementerian Lingkungan Hidup Republik Indonesia, Peraturan Menteri Lingkungan Hidup No. 5 Tahun 2014 tentang Baku Mutu Air Limbah. Jakarta, 2014.

N. Azizah, S. Rahmawati, and H. Prasetyo, “Studi adsorpsi fosfat menggunakan bahan alami,” Jurnal Teknologi Lingkungan, vol. 19, no. 1, pp. 45–54, 2018.

D. W. Breck, Zeolite molecular sieves: Structure, chemistry, and use. New York: Wiley, 1974.

F. A. Mumpton, “La roca magica: Uses of natural zeolites in agriculture and industry,” Proceedings of the National Academy of Sciences of the United States of America (PNAS), vol. 96, no. 7, pp. 3463–3470, 1999.

A. Farida, T. Suryani, and D. Lestari, “Potensi limbah kulit durian sebagai bahan baku karbon aktif,” Jurnal Rekayasa Material, vol. 12, no. 1, pp. 33–40., 2017.

E. Sudaryati, H. Prasetya, and A. Widodo, “Karbonisasi dan aktivasi kulit durian sebagai adsorben limbah cair,” Jurnal Sains dan Teknologi Lingkungan, vol. 6, no. 2, pp. 101–110, 2020.

M. A. Al-Anber, “Removal of phosphate ions from aqueous solutions using natural Jordanian zeolite modified with NaCl,” Applied Clay Science, vol. 107, pp. 165–173, 2015.

Q. Wu, Z. Li, H. Hong, K. Yin, and L. Tie, “Phosphate adsorption on natural and modified zeolites: Kinetics and mechanisms,” Desalination and Water Treatment, vol. 57, no. 11, pp. 5326–5337, 2016.

R. Situmeang, T. Manik, and H. Hasibuan, “Filter berbasis zeolit alam Pahae dan arang aktif kulit kakao untuk greywater treatment,” Jurnal Rekayasa Lingkungan, vol. 9, no. 2, pp. 77–85, 2021.

T. Nasution, S. Ginting, and R. Hutagalung, “Aktivasi karbon aktif kulit durian sebagai adsorben limbah laundry,” Jurnal Teknologi Material, vol. 5, no. 1, pp. 12–19, 2020.

R. Sihombing and A. Simanjuntak, “Pengaruh komposisi Zeolit Alam Pahae–Arang Aktif Kulit Kakao terhadap karakteristik porositas filter air,” Jurnal Fisika dan Aplikasinya, vol. 7, no. 2, pp. 53–60, 2021.

J. Lee and Y. C. Choi, "Pore Structure Characteristics of Foam Composite with Active Carbon," Materials, vol. 13, no. 18, p. 4038, 2020.

S. M. Auerbach, K. A. Carrado, and P. K. Dutta, Handbook of Zeolite Science and Technology. New York: Marcel Dekker, Inc, 2003.

A. Rahmi, “Pembuatan Karbon Aktif dari Batang Jagung dan Aplikasinya untuk Penjernih Air,” Jurnal Riset Fisika Edukasi dan Sains, vol. 7, no. 1, pp. 26-33, 2020.

G. A. Wardani, A. N. Octavia, M. Fathurohman, T. Hidayat, and E. Nofiyanti, “Chitosan Modified Sugarcane Bagasse Activated Charchoal as Tetracycline Adsorbent: Utilization of the column method,” Kovalen: Jurnal Riset Kimia, vol. 8, no. 3, pp. 280-29, 2022.

Susilawati, T. I. Nasution, and S. Khanifah, “The improvement of mechanical properties of hydrogen filter based on natural zeolite from pahae and clay addition,” Rasayan Journal of Chemistry, vol. 13, no. 3, pp. 1785-1791, 2021.

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Published

2025-11-16