Optical, Electrochemical, and Photovoltaic Evaluation of Suji Leaf (Dracaena angustifolia) Extract as a Natural Sensitizer for Dye-Sensitized Solar Cells
DOI:
https://doi.org/10.32734/jotp.v8i2.26017Keywords:
Chlorophyll, DSSC, Natural Dye, Photovoltaic, Suji Leaf, TiO2Abstract
A dye-sensitized solar cell (DSSC) is a third-generation solar cell technology that uses a dye as a sensitizer to convert light energy into electrical energy. This study aims to evaluate the potential of suji leaf extract (Dracaena angustifolia) as a natural dye for TiO₂-based DSSC using acetone and ethanol as solvents. Characterization was performed using UV-Vis, cyclic voltammetry (CV), and current–voltage (I–V) measurements. The UV-Vis results showed a maximum absorption peak at around 655 nm, indicating the dominance of chlorophyll pigments. The acetone extract produced higher absorbance and chlorophyll-a content than the ethanol extract. The CV results showed that the HOMO and LUMO energy levels of the acetone extract were −4.86 eV and −4.29 eV, respectively, whereas those of the ethanol extract were −4.90 eV and −4.44 eV. DSSC testing revealed that the acetone extract yielded a higher Voc value (0.0194 V) compared to the ethanol extract (0.0175 V), while both exhibited a Jsc value of 0.0667 mA·cm-2. The ethanol extract achieved a higher FF (57.9%) than the acetone extract (53.2%). The power conversion efficiencies obtained were 0.050% for the acetone solvent and 0.049% for the ethanol solvent. The results indicate that suji leaf has potential as a natural sensitizer in DSSC, with performance influenced by the choice of extraction solvent.
Downloads
References
[1] N. A. Pambudi et al., “Renewable Energy in Indonesia: Current Status, Potential, and Future Development,” Sustain., vol. 15, no. 3, p. 2342, 2023, doi: 10.3390/su15032342.
[2] N. A. Handayani and D. Ariyanti, “Potency of solar energy applications in Indonesia,” Int. J. Renew. Energy Dev., vol. 1, no. 2, pp. 33–38, 2012, doi: 10.14710/ijred.1.2.33-38.
[3] N. Shah et al., “A Review of Third Generation Solar Cells,” Processes, vol. 11, no. 6, p. 1852, 2023, doi: 10.3390/pr11061852.
[4] K. Sharma, V. Sharma, and S. S. Sharma, “Dye-Sensitized Solar Cells: Fundamentals and Current Status,” Nanoscale Res. Lett., vol. 13, p. 381, 2018, doi: 10.1186/s11671-018-2760-6.
[5] P. S. Saud et al., “Dye-sensitized solar cells: Fundamentals, recent progress, and Optoelectrical properties improvement strategies,” Opt. Mater. (Amst)., vol. 150, p. 115242, 2024, doi: 10.1016/j.optmat.2024.115242.
[6] B. Korir K, J. Kibet K, and S. Ngari M, “A review on the current status of dye‐sensitized solar cells:,” Energy Sci. Eng., vol. 12, pp. 3188–3226, 2024, doi: 10.1002/ese3.1815.
[7] T. Syed Hussain and W. Wei, “Technoeconomic Analysis of Dye Sensitized Solar Cells (DSSCs) with WS2/Carbon Composite as Counter Electrode Material,” Inorganics, vol. 10, no. 11, p. 191, 2022, doi: 10.3390/ inorganics10110191.
[8] J. Gong, J. Liang, and K. Sumathy, “Review on dye-sensitized solar cells (DSSCs): Fundamental concepts and novel materials,” Renew. Sustain. Energy Rev., vol. 16, no. 8, pp. 5848–5860, 2012, doi: 10.1016/j.rser.2012.04.044.
[9] N. Tomar, A. Agrawal, V. S. Dhaka, and P. K. Surolia, “Ruthenium complexes based dye sensitized solar cells: Fundamentals and research trends,” Sol. Energy, vol. 207, pp. 59–76, 2020, doi: 10.1016/j.solener.2020.06.060.
[10] L. Olteanu, R.-M. Ion, M. N. Ardeleanu, and A. I. Gheboianu, “Dyes for Dye-Sensitized Solar Cells (DSSCs): A Review,” Sci. Bull. Valahia Univ. - Mater. Mech., vol. 21, no. 24, pp. 7–12, 2025, doi: 10.2478/bsmm-2025-0001.
[11] S. Rahman et al., “Research on dye sensitized solar cells: recent advancement toward the various constituents of dye sensitized solar cells for efficiency enhancement and future prospects,” RSC Adv., vol. 13, no. 28, pp. 19508–19529, 2023, doi: 10.1039/d3ra00903c.
[12] P. Prakash and B. Janarthanan, “Review on the progress of light harvesting natural pigments as DSSC sensitizers with high potency,” Inorg. Chem. Commun., vol. 152, p. 110638, 2023, doi: 10.1016/j.inoche.2023.110638.
[13] U. Mahajan, K. Prajapat, M. Dhonde, K. Sahu, and M. Shirage, “Nano-Structures & Nano-Objects Natural dyes for dye-sensitized solar cells (DSSCs): An overview of extraction, characterization and performance,” Nano-Structures & Nano-Objects, vol. 37, p. 101111, 2024, doi: 10.1016/j.nanoso.2024.101111.
[14] S. Unwakoly, S. Hartati, H. Siti, H. Munawaroh, and P. Fitri, “Natural pigment-based dye-sensitized solar cells utilizing Caulerpa racemose and Gymnogongrus flabelliformis as photosensitizers,” Int. J. Renew. Energy Dev. J., vol. 14, no. 3, pp. 554–562, 2025, doi: 10.61435/ijred.2025.61083.
[15] D. Indrasti and N. Andarwulan, “Current Research in Nutrition and Food Science Stability of Chlorophyll as Natural Colorant: A Review for Suji (Dracaena angustifolia (Medik.) Roxb.) Leaves ’ Case,” Curr. Res. Nutr. Food Sci., vol. 06, no. 3, pp. 609–625, 2018, doi: 10.12944/CRNFSJ.6.3.04.
[16] E. Rahayuningsih, M. S. Pamungkas, M. Olvianas, and A. D. P. Putera, “Chlorophyll extraction from suji leaf (Pleomele angustifolia Roxb.) with ZnCl2 stabilizer,” J. Food Sci. Technol., vol. 55, no. 3, pp. 1028–1036, 2018, doi: 10.1007/s13197-017-3016-7.
[17] A. H. Ahliha, F. Nurosyid, and A. Supriyanto, “The Chemical Bonds Effect of Amaranthus Hybridus L . and Dracaena Angustifolia on TiO2 as Photo-sensitizer for Dye- Sensitized Solar Cells (DSSC),” in The 4th International Conference on Research, Implementation, and Education of Mathematics and Science (4th ICRIEMS), 2017, pp. 1–6. doi: 10.1063/1.4995165.
[18] R. R. Sova and P. Setiarso, “Studi Elektrokimia Klorofil dan Antosianin Sebagai Fotosensitizer DSSC (Dye-Sensitized Solar Cell): Electrochemical Study of Chlorophyll and Anthocyanin as DSSC (Dye-Sensitized Solar Cell) Photosensitizer,” Unesa J. Chem., vol. 10, no. 2, pp. 191–199, 2021, doi: 10.26740/ujc.v10n2.p191-199.
[19] P. Singh et al., “Dye-sensitized solar cells : Fundamentals, recent progress, and Optoelectrical properties improvement strategies,” Opt. Mater. (Amst)., vol. 150, p. 115242, 2024, doi: 10.1016/j.optmat.2024.115242.
[20] A. Kume, “Importance of the green color, absorption gradient, and spectral absorption of chloroplasts for the radiative energy balance of leaves,” J. Plant Res., vol. 130, no. 3, pp. 501–514, 2018, doi: 10.1007/s10265-017-0910-z.
[21] Y. Koyama, T. Miki, X. F. Wang, and H. Nagae, “Dye-sensitized solar cells based on the principles and materials of photosynthesis: Mechanisms of suppression and enhancement of photocurrent and conversion efficiency,” Int. J. Mol. Sci., vol. 10, no. 11, pp. 4575–4622, 2009, doi: 10.3390/ijms10114575.
[22] D. Arnon, “Copper Enzymes in Isolated Chloroplast Polyphenoloxidase in Beta Vulgaris,” Plant Physiol., vol. 24, no. 1, pp. 1–15, 1949, doi: 10.1104/pp.24.1.1.
[23] H. K. B. T.-M. in E. Lichtenthaler, “[34] Chlorophylls and carotenoids: Pigments of photosynthetic biomembranes,” in Plant Cell Membranes, vol. 148, Academic Press, 1987, pp. 350–382. doi: 10.1016/0076-6879(87)48036-1.
[24] A. R. Wellburn, “The Spectral Determination of Chlorophylls a and b, as well as Total Carotenoids, Using Various Solvents with Spectrophotometers of Different Resolution,” J. Plant Physiol., vol. 144, no. 3, pp. 307–313, 1994, doi: 10.1016/S0176-1617(11)81192-2.
[25] H. Tamiaki, “Chlorophyll Pigments and Their Synthetic Analogs Special Issue - Review,” vol. 00, no. 00, pp. 153–167, 2025, [Online]. Available: https://doi.org/10.1093/pcp/pcae094
[26] N. T. R. N. Kumara, A. Lim, C. M. Lim, M. I. Petra, and P. Ekanayake, “Recent progress and utilization of natural pigments in dye sensitized solar cells: A review,” Renew. Sustain. Energy Rev., vol. 78, pp. 301–317, 2017, doi: 10.1016/j.rser.2017.04.075.
[27] G. Calogero, J. Yum, A. Sinopoli, G. Di, and M. Gra, “Anthocyanins and betalains as light-harvesting pigments for dye-sensitized solar cells,” Sol. Energy, vol. 86, pp. 1563–1575, 2012, doi: 10.1016/j.solener.2012.02.018.
[28] S. Qamar and S. E. Ela, “ScienceDirect Dye-sensitized solar cells ( DSSC ): Principles , materials and working mechanism,” Curr. Opin. Colloid Interface Sci., vol. 74, p. 101871, 2024, doi: 10.1016/j.cocis.2024.101871.
[29] M. Grätzel, “Dye-sensitized solar cells,” vol. 4, pp. 145–153, 2003, doi: 10.1016/S1389-5567(03)00026-1.
[30] D. Sinha, D. De, and A. Ayaz, “Performance and stability analysis of curcumin dye as a photo sensitizer used in nanostructured ZnO based DSSC,” Spectrochim. Acta Part A Mol. Biomol. Spectrosc., vol. 193, pp. 467–474, 2018, doi: 10.1016/j.saa.2017.12.058.
[31] K. Prajapat, U. Mahajan, K. Sahu, M. Dhonde, and P. M. Shirage, “The Evolution of natural Dye-Sensitized solar Cells : Current Advances and future outlook,” Sol. Energy, vol. 284, no. July, p. 113081, 2024, doi: 10.1016/j.solener.2024.113081.
[32] A. Triyanto, N. Ali, H. Salleh, J. Setiawan, and N. I. Yatim, “Development of natural dye photosensitizers for dye-sensitized solar cells: a review,” Environ. Sci. Pollut. Res., vol. 31, no. 22, pp. 31679–31690, 2024, doi: 10.1007/s11356-024-33360-4.
[33] S. Malhotra, M. Ahmed, M. Gupta, and A. Ansari, “Metal-free and natural dye sensitized solar cells: Recent advancement and future perspectives,” Sustain. Energy Fuels, no. 18, pp. 4127–4163, 2024, doi: 10.1039/D4SE00406J.
[34] E. Cahya, P. Fitri, E. Suhendi, and B. Yuliarto, “Results in Optics Performance of dye-sensitized solar cells with mixed three natural pigments and reduced graphene oxide as a counter electrode,” Results Opt., vol. 14, p. 100592, 2024, doi: 10.1016/j.rio.2023.100592.
[35] S. Shalini, R. Balasundara, S. Prasanna, T. K. Mallick, and S. Senthilarasu, “Review on natural dye sensitized solar cell : Operation, materials and methods,” Renew. Sustain. Energy Rev., vol. 51, pp. 1306–1325, 2015, doi: 10.1016/j.rser.2015.07.052.
[36] G. Calogero, A. Bartolotta, G. Di Marco, A. Di Carlo, and F. Bonaccorso, “Vegetable-based dye-sensitized solar cells,” Chem. Soc. Rev., vol. 44, no. 10, pp. 3244–3294, 2015, doi: 10.1039/c4cs00309h.
[37] N. T. R. N. Kumara, A. Lim, C. Ming, and M. Iskandar, “Recent progress and utilization of natural pigments in dye sensitized solar cells : A review,” Renew. Sustain. Energy Rev., vol. 78, no. April, pp. 301–317, 2017, doi: 10.1016/j.rser.2017.04.075.
[38] L. Zhang and J. M. Cole, “Anchoring Groups for Dye-Sensitized Solar Cells,” ACS Appl. Mater. Interfaces, vol. 7, no. 6, pp. 3427–3455, 2015, doi: 10.1021/am507334m.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Journal of Technomaterial Physics

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.







